Factors affecting rejection during membrane separation

When the molecular weight is similar, linear molecules tend to have lower retention compared to branched or spherical molecules, which exhibit higher retention due to their more complex structures.

Several factors influence the rejection behavior during membrane separation processes:

1. **Relative Molecular Weight**: The size of the molecule plays a significant role in determining how effectively it is retained by the membrane.

2. **Molecular Properties**:
(1) Even when molecular weights are comparable, the shape of the molecule affects its retention. Linear molecules typically pass through the membrane more easily, while branched and spherical molecules are more likely to be retained.
(2) In charged membranes, the charge interaction between the membrane and solute significantly impacts rejection. Molecules with opposite charges to the membrane are less likely to be rejected, while those with the same charge face greater resistance.
(3) If the membrane has an adsorptive property toward a particular solute, the rejection rate of that solute increases as it becomes more tightly bound to the membrane surface.

3. **Effect of Other Polymer Solute**:
When multiple polymers are present in the solution, the rejection of one solute can increase compared to when it is alone. This is often attributed to concentration polarization, where the solute accumulates near the membrane surface, increasing the effective resistance.

4. **Operating Conditions**:
(1) As temperature increases, the viscosity of the solution decreases, which can lead to a reduction in the rejection rate.
(2) Higher flow velocity at the membrane surface helps reduce concentration polarization, thereby decreasing the rejection rate.
(3) At the isoelectric point of a protein, the net charge on the protein is zero, leading to minimal electrostatic repulsion. This allows for greater accumulation of proteins on the membrane surface, forming a thick gel polarization layer, which increases the resistance and thus the rejection of the solute.

These factors collectively determine the efficiency of membrane separation processes and are crucial in optimizing filtration systems for various applications.

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Editor: Hardware Business Network Information Center, http://news.chinawj.com.cn

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